The Ionization of Strong Electrolytes by Harkins W. D.

By Harkins W. D.

Show description

Read or Download The Ionization of Strong Electrolytes PDF

Best thermodynamics and statistical mechanics books

Physics and probability: essays in honor of E.T.Jaynes

The pioneering paintings of Edwin T. Jaynes within the box of statistical physics, quantum optics, and likelihood idea has had an important and lasting impression at the research of many actual difficulties, starting from basic theoretical questions via to functional purposes comparable to optical snapshot recovery.

State-Selected and State-to-State Ion-Molecule Reaction Dynamics. P. 2. Theory

The purpose of this sequence is to aid the reader receive basic information regarding a wide selection of issues within the huge box of chemical physics. specialists current analyses of matters of curiosity to stimulate new study and inspire the expression of person issues of view.

Additional info for The Ionization of Strong Electrolytes

Sample text

If we demand the packages to be smaller in the beginning, their spreading gets even worse. Considering this, it is questionable whether any explanation based on Hamiltonian dynamics in phase space or μ-space (cf. Sect. 1) can ever be a valid foundation of thermodynamics at all. This insufficiency of the classical picture becomes manifest at very low temperatures (freezing out inner degrees of freedom) and it is not obvious why it should become valid at higher temperatures even if it produces good results.

To understand this assumption in more detail, we consider an infinitesimal time step of the evolution of some special function f depicted in Fig. 1. We restrict ourselves here to a two-dimensional “gas”; nevertheless, the μ-space is already four-dimensional, thus we have to visualize f by projections. The special function f corresponds to a situation with all particles concentrated in one cell in configuration space but moving in opposite directions with the same velocity. By some “center of mass” coordinate transformation any collision process may by mapped on this one.

J. html (2002) 23 7. D. Mahan, Many-Particle Physics, 3rd edn. (Plenum Press, New York, London, 2000) 32 8. E. Jaynes, Phys. Rev. 106, 620 (1957) 37 9. E. Jaynes, Phys. Rev. 108, 171 (1957) 37 Chapter 4 Brief Review of Pertinent Concepts Given the success of Ludwig Boltzmann’s statistical approach in explaining the observed irreversible behavior of macroscopic systems . . , it is quite surprising that there is still so much confusion about the problem of irreversibility. — J. L. Lebowitz [1] Boltzmann’s ideas are as controversial today, as they were more than hundred years ago, yet they are still defended (Lebowitz 1993).

Download PDF sample

Rated 4.35 of 5 – based on 40 votes