Compound Forming Extractants, Solvating Solvents and Inert by Y. Marcus, E. Yanir, A. S. Kertes

By Y. Marcus, E. Yanir, A. S. Kertes

Equilibrium Constants of Liquid-Liquid Distribution Reactions, half III: Compound Forming Extractants, Solvating Solvents, and Inert Solvents makes a speciality of the compilation of equilibrium constants of assorted compounds, equivalent to acids, ions, salts, and aqueous suggestions.
The manuscript provides tables that convey the distribution reactions of carboxylic and sulfonic acid extractants and their dimerization and different reactions within the natural part and extraction reactions of steel ions from aqueous ideas. The booklet additionally states that the inorganic anions in those strategies are inappropriate, for the reason that they don't participate in the extraction response.
The booklet examines tables that illustrate the distribution of inorganic acids, salts, and complexes among aqueous recommendations and solvents that experience oxygen donor atoms. Tables that exhibit the distribution of inorganic acids, salts, and complexes among aqueous recommendations and inert solvents that don't have donor atoms and sometimes applied as inert diluents also are awarded.
The manuscript is a crucial reference for readers and researchers drawn to the equilibrium constants of compounds.

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Acta Chem. Scand. , U_, 329 (1957). F. and Scargill, D. , J. Chem. S o c , 90 (1961). Hogfeldt, E. and Bolander, B. , Arkiv. , 7A_y 161 (1963). Siekierski, S. and Olszer, R. , J. Inorg. Nucl. , 25_, 1351 (1963). Hogfeldt, E. and Rasmusson, K. , Svenk. Kern. , 78_, 490 (1966). Olszer, R. , J. Inorg. Nucl. , 28^, 1991 (1966). , J. Phys. , 2, 51 (1898). R E A C T I O N 98B M METAL ION, CONDITIONS, AQ. CONDITIONS, ORG. REF. 39 H g ++ Ligand Ag + Ligand: Ligand: + M = M 2S + M + + M + = MS MA 2 = MA^" H + + A~ = HA CI",A" MS + ++ ++ ++ = M 2S M+ + S = MS+ MS + M+ + S = MS+ MS + M+ + S = MS+ H + + A" = HA N03",A- + R E A C T I O N o,m,p-Xylene, S H 20 = H^O H 20 Extractant: M METAL ION.

Nucl. , 32, 987 (1970). 8 20 20 20 20 TEMP. 8 K Kettrup, A. , Z. Anal. , 250, 241 (1967). + 3S = MA 3-3S AH AH AH AH LOG 67K I HA = HA C 2H 5COO",A Ligand: + 3A M +2 + 2A~ + 2S = MA2-2S M +2 I~,A~ | H 20 + S = H 20-S H 20 +3 Bi Hg Ligand: Ligand: M +3 + 3A" + 3S = MA3-3S +3 Fe | HA + S = HA-S CNS~,A~ Cvclohexanone, S R E A C T I O N Ligand: Extractant: M METAL ION, S S S S S S CONDITIONS, ORG. 70K 67K 67K 67K 67K 67K REF. 30 Ligand: +4 Ge Ligand: +4 Ge ^ Ligand: +4 Ge K TEMP. 58 20 20 20 CONDITIONS.

5 (Na ,H ) C10 4 CONDITIONS. S S S S S S S S S S S CONDITIONS. ORG. ' 62T 62T 67K 62T 67K 56K 62T 62T 62T 62T 62T 64 D REF. 7 K 20 20 Dyrssen, D. , J. Inorg. Nucl. , 26_, 981 (1964). Kettrup, A. , Z, Anal. , 230, 241 (1967). 64D 67K References -1 4 -4 9 '25 20 20 TEMP. Tribalat, S. and Zeller, C , Bull. Soc. Chim, France, 2041 (1962). AH 4. , Jenner Publ. Rept. No. 11 (1956). + A~ = MA = MA 2 •2S O 56K + 1 = MA 3 3S MA 4-2S" HMA 4 2S 3S C T Irving, H. C. , J. Chem. S o c , 1927 (1955). M CH3COO", A" MA 4" + 2S H M M Br~,A~ R E A 551 Ligand: Bi I„ Hg Fe +3 Ligand: M METAL ION, AQ.

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