Chemical Reaction Engineering Reviews—Houston by Dan Luss and Vern W. Weekman, Jr. (Eds.)

By Dan Luss and Vern W. Weekman, Jr. (Eds.)

content material: Chemical reactor modeling : the fascinating and the achieveable / R. Shinnar --
Liquid-supported catalysts / C.N. Kenney --
Coal conversion response engineering / C.Y. Wen and S. Tone --
shipping phenomena in packed mattress reactors / E.U. Schlünder --
Environmental response engineering / John H. Seinfeld --
The layout of gas-solids fluid mattress and comparable reactors / W.P.M. Van Swaaij --
Gas-liquid reactors / J.C. Charpentier --
Biochemical response engineering / Arthur E. Humphrey --
Catalyst deactivation / John B. Butt and Rustom M. Billimoria.

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We can get a b e t t e r r e p r e s e n t a t i o n of composition and feed-stock e f f e c t s by more r e f i n e d lumping schemes, such as the one g i v e n by Jacobs (52). (See F i g . 7 ) . Here, the e s t i m a t i o n of the f i r s t order m a t r i x i s more d i f f i c u l t , as most o f the r e a c t i o n s are n e a r l y i r r e v e r s i b l e and the lumps are improper lumps F u r t h e r , any modeling w i l l i n v o l v e much stronger s i m p l i f i c a t i o n assumptions as compared to the x y l ene use.

P. (1960) Trans. Inst. Chem. Eng. 38, 125. 42. Argyriou, D . I . L. and Shinnar, R. (1971) AIChE J . 17, 122C. 43. Krambeck, F . , Shinnar, R. (1969) Chem. Eng. Sci. 24, 1497. 44. W. Jr. (1968), I&EC Process Des. Dev. 1, 90. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1978. ch001 36 45. Wei, J. Catalysis and Reactors (1969) CEP monograph series, vol. 65. 46. W. , XIV Automotive Technical Congress, FISITA, London June 1972. 47. B. This symposium. 48. Shinnar, R. Tracer experiments i n reactor design, paper given at B.

A c o m p l i c a t i n g f a c t o r which can obscure m e c h a n i s t i c s t u d i e s o f such systems i s t h e f o r m a t i o n o f m e t h y l c h l o r i d e b y a p a r a l l e l gas phase r e a c t i o n , and c o n d i t i o n s can be f o u n d w h i c h g i v e more h i g h l y h a l o g e n a t e d s p e c i e s . A wide range o f r e l a t e d i n v e s t i g a t i o n s have b e e n r e p o r t e d . I m p e r i a l C h e m i c a l I n d u s t r i e s s t a t e s (5) t h a t t h e c h l o r i n a t i o n o f p a r a f f i n s , o l e f i n s , b e n z e n e , a n d b e n z e n e h o m o l o g s c a n be e f f e c t e d b y c o n t a c t i n g them w i t h a LiC£/PdC£2 m e l t w i t h a l k a l i o r a l k a l i n e e a r t h a d d i t i v e s t o keep t h e m e l t i n g p o i n t below 275°C.

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